It's a hash table containing the possible pgf options for graphic primitives that can be used to create a pgf picture. Options not listed here will usually be discarded.
The object possiblePGFOptions is a hash table.
The source of this document is in /build/reproducible-path/macaulay2-1.25.05+ds/M2/Macaulay2/packages/Graphics.m2:1632:0.